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[Be(dad) 2 ]: Synthesis and Structure of a Diazabutadieneberyllium Complex
Author(s) -
Thiele KarlHeinz,
Lorenz Volker,
Thiele Gerhard,
Zönnchen Peter,
Scholz Joachim
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199413721
Subject(s) - beryllium , intramolecular force , ligand (biochemistry) , chemistry , chloride , sodium , photochemistry , medicinal chemistry , stereochemistry , organic chemistry , receptor , biochemistry
The reaction of beryllium chloride, the appropriate diazabutadiene, and sodium provides the beryllium complex 1 . Its ligands are present as radical anions in solution. On addition of THF a diazabutadiene ligand is released by intramolecular electron transfer and an enediamide complex forms. R = C 6 H 5 , R 1 = C 6 H 4 CH 3 .
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