Iterative Divergent/Convergent Approach to Linear Conjugated Oligomers by Successive Doubling of the Molecular Length: A Rapid Route to a 128Å‐Long Potential Molecular Wire | Zendy

Schumm Jeffry S. | Zendy; Pearson Darren L. | Zendy; Tour James M. | Zendy

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Iterative Divergent/Convergent Approach to Linear Conjugated Oligomers by Successive Doubling of the Molecular Length: A Rapid Route to a 128Å‐Long Potential Molecular Wire

Author(s) -

Schumm Jeffry S.,

Pearson Darren L.,

Tour James M.

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199413601

Subject(s) - conjugated system , molecular wire , molecular electronics , sequence (biology) , coupling (piping) , combinatorial chemistry , chemistry , materials science , nanotechnology , molecule , stereochemistry , computational chemistry , organic chemistry , polymer , biochemistry , metallurgy

An iodination, a protodesilylation, and a Pd/Cu‐catalyzed cross coupling are the three reactions needed to successively double the length of molecular units to form 1 , a 128 Å long linear 16‐mer, in a doubling sequence with only four iterations. Compound 1 could possibly serve as a molecular wire in molecular electronics studies.

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