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[Cu 96 P 30 {P(SiMe 3 ) 2 } 6 (PEt 3 ) 18 ], a New Phosphorus‐Bridged Copper Cluster
Author(s) -
Fenske Dieter,
Holstein Werner
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199412901
Subject(s) - cluster (spacecraft) , copper , phosphorus , chemistry , crystallography , computer science , organic chemistry , programming language
One of the largest cluster complexes whose structure has been elucidated is the title compound, which is formed from CuCl, PEt 3 , and P(SiMe 3 ) 3 , when the components are used in the ratio 1:0.5:0.6. The structure, which is difficult to describe, can be discussed as an intermediate in the formation of binary Cu 3 P.