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Base‐Free Monomeric Organogallium Hydrides
Author(s) -
Cowley Alan H.,
Gabbaï François P.,
Isom Harold S.,
Carrano Carl J.,
Bond Marcus R.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199412531
Subject(s) - gallium , chemistry , monomer , base (topology) , kinetic energy , medicinal chemistry , computational chemistry , organic chemistry , mathematics , physics , mathematical analysis , quantum mechanics , polymer
Stable tricoordinate mono‐ and dihydrides of gallium, 1 and [(Ar)Ga(H) 2 ], respectively, can be isolated by taking advantage of the kinetic stabilization afforded by bulky Ar substituents. The monohydride 1 , prepared from [(Ar) 2 GaCl] and Li‐GaH 4 , is the product of an unusual rearrangement reaction. Ar = 2,4,6‐ t BuC 6 H 2 .
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