Catalytic Pt + ‐Mediated Oxidation of Methane by Molecular Oxygen in the Gas Phase | Zendy

Wesendrup Ralf | Zendy; Schröder Detlef | Zendy; Schwarz Helmut | Zendy

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Catalytic Pt + ‐Mediated Oxidation of Methane by Molecular Oxygen in the Gas Phase

Author(s) -

Wesendrup Ralf,

Schröder Detlef,

Schwarz Helmut

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199411741

Subject(s) - catalysis , formaldehyde , methane , formic acid , methanol , chemistry , desorption , oxygen , inorganic chemistry , anaerobic oxidation of methane , gas phase , catalytic cycle , catalytic oxidation , photochemistry , organic chemistry , adsorption

The first catalytic oxidative activation of methane in the gas phase employs high‐vacuum conditions and Pt + ions generated by laser desorption. In the presence of O 2 the initially generated Pt + CH 2 is oxidized to formic acid (65%), formaldehyde (25%), and methanol (10%). The picture on the right shows the most important part of the complicated catalytic cycle.

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