Synthesis, Structures, and Reactions of Two Bis(diaminostannylene)s and a Bis(diaminogermylene) Containing a Central C 6  Ring | Zendy

Braunschweig Holger | Zendy; Hitchcock Peter B. | Zendy; Lappert Michael F. | Zendy; Pierssens Luc J.M. | Zendy

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Synthesis, Structures, and Reactions of Two Bis(diaminostannylene)s and a Bis(diaminogermylene) Containing a Central C 6 Ring

Author(s) -

Braunschweig Holger,

Hitchcock Peter B.,

Lappert Michael F.,

Pierssens Luc J.M.

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199411561

Subject(s) - cyclohexane , ring (chemistry) , benzene , tin , chemistry , metal , redox , medicinal chemistry , stereochemistry , crystallography , inorganic chemistry , organic chemistry

Two Sn[N(SiMe 3 ) 2 ] moieties arranged trans , linked by a 1,4‐diaminosubstituted cyclohexane or benzene ring describes the first heteroleptic bis(stannylene)s 1 and 2 (R = SiMe 3 ), respectively; the bis(germylene) is isomorphous with 2 . The replacement of the N(SiMe 3 ) 2 groups for aryloxy groups takes place on addition of Sn(OAr) 2 to 1 and 2 ; surprisingly, the treatment of 2 with SnCl 2 affords the redox products 3 and metallic tin.

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