Tetraoxa[22]porphyrin(2.2.2.2) Dication and Tetraoxa[24]porphyrinogens(2.2.2.2) | Zendy

Märkl Gottfried | Zendy; Sauer Heinrich | Zendy; Kreitmeier Peter | Zendy; Burgemeister Thomas | Zendy; Kastner Fritz | Zendy; Adolin Georg | Zendy; Nöth Heinrich | Zendy; Polborn Kurt | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Tetraoxa[22]porphyrin(2.2.2.2) Dication and Tetraoxa[24]porphyrinogens(2.2.2.2)

Author(s) -

Märkl Gottfried,

Sauer Heinrich,

Kreitmeier Peter,

Burgemeister Thomas,

Kastner Fritz,

Adolin Georg,

Nöth Heinrich,

Polborn Kurt

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199411511

Subject(s) - dication , porphyrin , antiaromaticity , chemistry , photochemistry , medicinal chemistry , crystallography , ion , aromaticity , molecule , organic chemistry

Very flexible and antiaromatic versus relatively rigid and aromatic —that is the difference between [24]porphyrinogen 1 and its oxidation product [22]porphyrin dication 2 . Although both compounds occur in the cis, trans, cis, trans configuration, the protons along the inner perimeter of 2 are shifted roughly 20.5 ppm upfield, and the outer protons are shifted approximately 8.4 ppm downfield relative to the corresponding protons in 1 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research