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High‐Pressure Synthesis of K 2 PtH 6 , a Saltlike Hydride with the K 2 PtCl 6 Structure
Author(s) -
Bronger Welf,
Auffermann Gudrun
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199411121
Subject(s) - hydride , ternary operation , halide , high pressure , transition metal , metal , chemistry , metal halides , inorganic chemistry , materials science , metallurgy , thermodynamics , organic chemistry , catalysis , computer science , physics , programming language
At H 2 pressures of up to 2 kbar , new ternary transition metal hydride complexes can be synthesized in which the transition metal has the same high oxidation state as in the corresponding ternary halides. In K 2 PtH 6 , which was prepared by this method, the complex [PtH 6 ] 2− building unit 1 was observed.
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