Functionalization of C 60  Buckminsterfullerene by [8 + 2] Cycloaddition: Spectroscopic and Electron‐Transfer Properties of a Tetrahydroazulenofullerene | Zendy

Beer Ernst | Zendy; Feuerer Michaela | Zendy; Knorr Andreas | Zendy; Mirlach Albert | Zendy; Daub Jörg | Zendy

Premium

Functionalization of C 60 Buckminsterfullerene by [8 + 2] Cycloaddition: Spectroscopic and Electron‐Transfer Properties of a Tetrahydroazulenofullerene

Author(s) -

Beer Ernst,

Feuerer Michaela,

Knorr Andreas,

Mirlach Albert,

Daub Jörg

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199410871

Subject(s) - buckminsterfullerene , fullerene , cycloaddition , electron transfer , surface modification , chemistry , adduct , photochemistry , ion , fullerene chemistry , computational chemistry , organic chemistry , catalysis

The novel C 60 cycloadduct 1 is formed in the reaction of 8‐methoxyheptafulvene with buckminster‐fullerene C 60 . Compound 1 can be reduced to its tetraanion in four reversible steps; the spectral properties of the radical anion, dianion, and trianion were examined by UV/VIS/NIR spectroelectro‐chemistry. Adduct 1 may lead to other functional‐ized fullerenes having substructures with electron‐transfer properties.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research