Synthesis and Structural Characterization of [{(Et 2 O)Mg} 6 (NPh) 4 Br 4 ]: A Magnesium–Imide Cage Species Derived from a Dimagnesylamine Solution | Zendy

Hascall Tony | Zendy; Olmstead Marilyn M. | Zendy; Power Philip P. | Zendy

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Synthesis and Structural Characterization of [{(Et 2 O)Mg} 6 (NPh) 4 Br 4 ]: A Magnesium–Imide Cage Species Derived from a Dimagnesylamine Solution

Author(s) -

Hascall Tony,

Olmstead Marilyn M.,

Power Philip P.

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199410001

Subject(s) - molecule , crystallography , magnesium , chemistry , ether , ion , imide , cage , hexagonal crystal system , trigonal crystal system , diethyl ether , stereochemistry , x ray crystallography , characterization (materials science) , crystal structure , inorganic chemistry , materials science , polymer chemistry , organic chemistry , diffraction , nanotechnology , physics , combinatorics , mathematics , optics

Grignard compounds and amines were converted into “dimagnesylamines” RN‐(MgX) 2 as long ago as 1903. Now for the first time a crystalline compound has been obtained from a PhN(MgBr) 2 solution in ether and characterized by X‐ray structure analysis. The title compound has a Mg 6 N 4 adamantanyl framework; each Mg 2+ ion is solvated by an ether molecule, and the four Br − ions are located above the four hexagonal faces of the Mg 6 N 4 cage.

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