Iodine Chains in (Me 4 Sb) 3 I 8  and Discrete Triiodide Ions in Me 4 AsI 3 | Zendy

Behrens Ulrich | Zendy; Breunig Hans Joachim | Zendy; Denker Michael | Zendy; Ebert Klaus Heinz | Zendy

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Iodine Chains in (Me 4 Sb) 3 I 8 and Discrete Triiodide Ions in Me 4 AsI 3

Author(s) -

Behrens Ulrich,

Breunig Hans Joachim,

Denker Michael,

Ebert Klaus Heinz

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199409871

Subject(s) - triiodide , ion , iodine , chemistry , materials science , radiochemistry , inorganic chemistry , analytical chemistry (journal) , metallurgy , environmental chemistry , organic chemistry , electrode , dye sensitized solar cell , electrolyte

Golden lustrous crystals of the semiconductor Me 4 SbI 8 contain free ordered iodine chains (picture shown on the right), which are stabilized by the coordination of three Me 4 Sb + ions to every second I atom of the chain. These chains break if the octaiodide is dissolved. Me 4 SbI 8 can be prepared readily from Me 4 SbI and I 2 .

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