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Reactions of an Iminophosphoranylidene Carbenoid
Author(s) -
Schilbach Wolfgang,
von der Gönna Volker,
Gudat Dietrich,
Nieger Martin,
Niecke Edgar
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199409821
Subject(s) - carbenoid , phosphorane , methylene , chemistry , stereochemistry , medicinal chemistry , computational chemistry , organic chemistry , catalysis , rhodium
Interesting trapping products with phosphanes and chlorotrimethylsilane result from reactions with the novel intermediate phosphoranylidene carbenoid 1 : These lead to the phosphoniomethanide 2 with PPh 3 , the dihydrodiphosphete 3 with PMe 3 , and the imino(methylene)phosphorane 4 with ClSiMe 3 . R = 2,4,6‐ t Bu 3 C 6 H 2 , R′ = Ph, Me.