Reactions of [(C 5 Me 5 )ZrF 3 ] with AlMe 3 –Synthesis and Structure of a Zirconium–Aluminum–Carbon Cluster | Zendy

Herzog Axel | Zendy; Roesky Herbert W. | Zendy; Zak Zdirad | Zendy; Noltemeyer Mathias | Zendy

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Reactions of [(C 5 Me 5 )ZrF 3 ] with AlMe 3 –Synthesis and Structure of a Zirconium–Aluminum–Carbon Cluster

Author(s) -

Herzog Axel,

Roesky Herbert W.,

Zak Zdirad,

Noltemeyer Mathias

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199409671

Subject(s) - zirconium , aluminium , carbon fibers , cluster (spacecraft) , catalysis , cube (algebra) , materials science , metal , crystallography , chemistry , metallurgy , composite material , mathematics , organic chemistry , combinatorics , composite number , computer science , programming language

Transfer of methyl groups from 2 to 1 leads to the first Zr 3 Al 6 C 7 cluster 3 [Eq. (a)], in which six metal atoms form an open cube shielded by Al and C atoms. The ZrAl distances in the cube are remarkably short. Zr/Al/C compounds are of interest with regard to Ziegler–Natta catalysts.

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