Premium
Concerning the Mechanism of α‐Elimination: Hypervalent Ion Pairing in an Iodocarbenium Iodide
Author(s) -
Weiss Robert,
Rechinger Michael,
Hampel Frank
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199408931
Subject(s) - hypervalent molecule , iodide , halogen , chemistry , ion , sequence (biology) , crystallography , iodine , inorganic chemistry , organic chemistry , biochemistry , alkyl
The first crystalline iodocarbenium iodide 1 has an almost linear CII sequence, as revealed by the X‐ray structure analysis. Thus 1 contains a new hypervalent three‐center, four‐electron bonding system and marks a characteristic point on the general reaction coordinate of the polar α‐di‐halogen elimination.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom