Premium
Electrostatic Activation of Hypervalent Organo‐Iodine Compounds: Bis(onio)‐Substituted Aryliodine( III ) Salts
Author(s) -
Weiss Robert,
Seubert Jörg
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199408911
Subject(s) - hypervalent molecule , chemistry , diazo , iodine , combinatorial chemistry , organic chemistry , iodine compounds , medicinal chemistry
A new class of compounds , for example 2 , synthesized from 1 or iodosobenzene, are the title compounds in this article. The oxidation potential of 1 is increased considerably by bis(onio) substitution; thus, these new systems can be used as potent oxidants. Applications include dehydrogenations of monohydrazones to give diazo compounds and of 1,2‐bishydrazones to give alkynes.