Preparation of Chiral Nitroxide Radicals and Spontaneous Optical Resolution by Recrystallization | Zendy

Tamura Rui | Zendy; Susuki Shinsuke | Zendy; Azuma Nagao | Zendy; Matsumoto Akira | Zendy; Toda Fumio | Zendy; Kamimura Akio | Zendy; Hori Kenzi | Zendy

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Preparation of Chiral Nitroxide Radicals and Spontaneous Optical Resolution by Recrystallization

Author(s) -

Tamura Rui,

Susuki Shinsuke,

Azuma Nagao,

Matsumoto Akira,

Toda Fumio,

Kamimura Akio,

Hori Kenzi

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199408781

Subject(s) - recrystallization (geology) , radical , nitroxide mediated radical polymerization , enantiomer , photochemistry , resolution (logic) , materials science , enantiomeric excess , chemistry , crystallography , stereochemistry , organic chemistry , polymer , radical polymerization , enantioselective synthesis , catalysis , polymerization , paleontology , artificial intelligence , computer science , biology

Conglomerates of enantiomeric single crystals are formed on slow recrystallization of the chiral nitroxide radicals 1, R H, Me, obtained according to reaction (a). The unusual arrangement of 1 in the crystal may explain the spontaneous optical resolution.

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