Hexaspiro[2.4.2.4.2.4.2.4.2.4.2.4]dotetraconta‐4,6,11,13,18,20,25,27,32,34,39,41‐dodecayne An Exploding [6]Rotane | Zendy

de Meijere Armin | Zendy; Kozhushkov Sergei | Zendy; Puls Carsten | Zendy; Haumann Thomas | Zendy; Boese Roland | Zendy; Cooney Mark J. | Zendy; Scott Lawrence T. | Zendy

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Hexaspiro[2.4.2.4.2.4.2.4.2.4.2.4]dotetraconta‐4,6,11,13,18,20,25,27,32,34,39,41‐dodecayne An Exploding [6]Rotane

Author(s) -

de Meijere Armin,

Kozhushkov Sergei,

Puls Carsten,

Haumann Thomas,

Boese Roland,

Cooney Mark J.,

Scott Lawrence T.

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199408691

Subject(s) - trimer , product (mathematics) , oxidative coupling of methane , coupling (piping) , chemistry , stereochemistry , computational chemistry , crystallography , materials science , mathematics , organic chemistry , dimer , geometry , methane , metallurgy

The oxidative coupling of the acyclic trimer of 1,1 ‐di‐ethynylcyclopropane gives title compound 1 as the main product. X‐ray structural analysis of 1 shows that the spirocyclopropane and adjacent butadiyne units have a distinct electronic interaction. A dehydrononamer (C 63 H 36 ) was also isolated.

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