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Hexaspiro[2.4.2.4.2.4.2.4.2.4.2.4]dotetraconta‐4,6,11,13,18,20,25,27,32,34,39,41‐dodecayne An Exploding [6]Rotane
Author(s) -
de Meijere Armin,
Kozhushkov Sergei,
Puls Carsten,
Haumann Thomas,
Boese Roland,
Cooney Mark J.,
Scott Lawrence T.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199408691
Subject(s) - trimer , product (mathematics) , oxidative coupling of methane , coupling (piping) , chemistry , stereochemistry , computational chemistry , crystallography , materials science , mathematics , organic chemistry , dimer , geometry , methane , metallurgy
The oxidative coupling of the acyclic trimer of 1,1 ‐di‐ethynylcyclopropane gives title compound 1 as the main product. X‐ray structural analysis of 1 shows that the spirocyclopropane and adjacent butadiyne units have a distinct electronic interaction. A dehydrononamer (C 63 H 36 ) was also isolated.