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Organoplatinum Dendrimers Formed by Oxidative Addition
Author(s) -
Achar Sudhir,
Puddephatt Richard J.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199408471
Subject(s) - dendrimer , oxidative addition , pyridine , oxidative phosphorylation , chemistry , alkyl , stereochemistry , combinatorial chemistry , organic chemistry , biochemistry , catalysis
A Pt 14 dendrimer is the highest nuclearity complex obtained by the first convergent method for the synthesis of alkyl transition metal dendrimers. The product of the first growth cycle is 1 , which forms by oxidative addition of 4,4′‐bis(bromomethyl)‐2,2′‐bi‐pyridine to [Me 2 Pt( t Bu 2 bpy)] and subsequent introduction of a Pt II center with [Pt 2 Me 4 ‐(μ‐SMe 2 )].
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