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Jacobson and Heintschel Peroxides
Author(s) -
Jang SeiHum,
Gopalan Prakash,
Jackson James E.,
Kahr Bart
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199407751
Subject(s) - radical , parallels , chemistry , dimer , biochemistry , organic chemistry , mechanical engineering , engineering
The structure of the peroxides 1 , which arise on oxidation of the corresponding triarylmethyl radicals in air, remained unrecognized for a long time. The false assumption that triarylmethyl radicals are linked methyl‐to‐methyl on peroxidation parallels the earlier misconception that triphenylmethyl dimer was hexaphenylethane. R H, OCH 3 .
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