Aurophilicity at Sulfur Centers: Synthesis and Structure of the Tetragold( I ) Species [(Ph 3 PAu) 4 S](CF 3 SO 3 ) 2  · 2CH 2 Cl 2 | Zendy

Canales Fernando | Zendy; Gimeno M. Concepción | Zendy; Jones Peter G. | Zendy; Laguna Antonio | Zendy

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Aurophilicity at Sulfur Centers: Synthesis and Structure of the Tetragold( I ) Species [(Ph 3 PAu) 4 S](CF 3 SO 3 ) 2 · 2CH 2 Cl 2

Author(s) -

Canales Fernando,

Gimeno M. Concepción,

Jones Peter G.,

Laguna Antonio

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199407691

Subject(s) - tetragonal crystal system , sulfur , crystallography , chemistry , atom (system on chip) , physics , stereochemistry , mineralogy , crystal structure , computer science , organic chemistry , embedded system

More than three PR 3 Au ligands were coordinated for the first time to an element of the sixth main group: the μ 4 ‐S atom of the title compound occupies the apical position in the tetragonal pyramidal framework (shown on the right); its four Au atoms are arranged in a butterfly form with a hinge angle of 30°.

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