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The Oxovanadium–Organoarsonate System: [2CH 3 OH ⊂ V 12 O 14 (OH) 4 (PhAsO 3 ) 10 ] 4− and [2H 2 O ⊂ V 12 O 12 (OH) 2 (H 2 O) 2 (PhAsO 3 ) 10− (PhAsO 3 H) 4 ] 2− , Clusters with Nanometer Dimensions and Cavities for Neutral Molecules
Author(s) -
Khan M. Ishaque,
Zubieta Jon
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199407601
Subject(s) - cluster (spacecraft) , molecule , crystallography , chemistry , materials science , analytical chemistry (journal) , inorganic chemistry , organic chemistry , computer science , programming language , chromatography
Neutral molecules are encapsulated in the cluster anions in the title, which were produced by solvothermal reactions of [ n Bu 4 N] 3 [H 3 V 10 O 28 ] and PhAsO 3 H 2 in CH 3 OH/H 2 O (99:1) with and without Et 4 NCl. The structures are shown schematically below.