μ‐Oxodiiron( III ) Complexes of Porphycenes | Zendy

Lausmann Michael | Zendy; Zimmer Ingeborg | Zendy; Lex Johann | Zendy; Lueken Heiko | Zendy; Wieghardt Karl | Zendy; Vogel Emanuel | Zendy

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μ‐Oxodiiron( III ) Complexes of Porphycenes

Author(s) -

Lausmann Michael,

Zimmer Ingeborg,

Lex Johann,

Lueken Heiko,

Wieghardt Karl,

Vogel Emanuel

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199407361

Subject(s) - porphyrin , steric effects , chemistry , stereochemistry , crystallography , organic chemistry

Far‐reaching analogies between μ‐oxodiiron( III ) complexes of porphycenes and porphyrins with regard to physical, chemical, and structural properties are revealed by investigations of the new metallopor‐phycenes 1 (R n Pr, t Bu). These are obtained by using standard methods for porphyrin chemistry. The Fe‐O‐Fe angle in 1 (R n Pr) differs widely (145°) from those of the metalloporphyrins (161–180°) and that of 1 (R t Bu; 179°) as a result of reduced steric interactions.

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