Discrete M 6 N Octahedra in the Subnitrides Na 16  Ba 6 N and Ag 16 Ca 6 N: A Reconsideration of the Ag 8 Ca 3  Structure Type | Zendy

Snyder G. Jeffrey | Zendy; Simon Arndt | Zendy

Premium

Discrete M 6 N Octahedra in the Subnitrides Na 16 Ba 6 N and Ag 16 Ca 6 N: A Reconsideration of the Ag 8 Ca 3 Structure Type

Author(s) -

Snyder G. Jeffrey,

Simon Arndt

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199406891

Subject(s) - octahedron , crystallography , atom (system on chip) , metal , chemistry , materials science , crystal structure , metallurgy , computer science , embedded system

The future of subnitride chemistry appears promising : M 6 octahedra with a central N atom have been detected in the new compound Na 16 Ba 6 N and in the compound hitherto described as “Ag 8 Ca 3 ”; the latter is actually the isotypic Ag 16 Ca 6 N (with 0.7% N)! In these compounds the M 6 N octahedra are embedded in a matrix of Na and Ag, respectively. Numerous phases with the Ag 8 Ca 3 structure such as Ni 6 Si 2 M 3 and Ni 6 Al 2 M 3 (M = rare‐earth metal) may likewise be stabilized by interstitial atoms.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research