Synthesis and Third‐Order Nonlinear Optical Properties of a Conjugated Porphyrin Polymer | Zendy

Anderson Harry L. | Zendy; Martin Simon J. | Zendy; Bradley Donal D. C. | Zendy

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Synthesis and Third‐Order Nonlinear Optical Properties of a Conjugated Porphyrin Polymer

Author(s) -

Anderson Harry L.,

Martin Simon J.,

Bradley Donal D. C.

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199406551

Subject(s) - porphyrin , conjugated system , polymer , spectral line , materials science , absorption (acoustics) , nonlinear optical , absorption spectroscopy , nonlinear system , enhanced data rates for gsm evolution , order (exchange) , photochemistry , optoelectronics , optics , chemistry , physics , quantum mechanics , telecommunications , computer science , composite material , finance , economics

The π–π * absorption edge (Q band) of the soluble porphyrin polymer 1 lies in the IR region and is unusually intense. Electroabsorption (Stark) spectra demonstrate that polymer 1 has an exceptionally large third‐order nonlinear susceptibility.

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