Construction of Carbon Frameworks with the Help of Ruthenium Complexes: 1,5‐Cyclooctadiene as a Reagent in Transition Metal Catalyzed Reactions | Zendy

Butenschön Holger | Zendy

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Construction of Carbon Frameworks with the Help of Ruthenium Complexes: 1,5‐Cyclooctadiene as a Reagent in Transition Metal Catalyzed Reactions

Author(s) -

Butenschön Holger

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199406361

Subject(s) - 1,5 cyclooctadiene , ruthenium , cyclooctadiene , chemistry , catalysis , transition metal , reagent , ligand (biochemistry) , medicinal chemistry , metal , polymer chemistry , organic chemistry , biochemistry , receptor

Hitherto 1,5‐cyclooctadiene (COD) was used almost exclusively as a ligand in transition metal complexes; however, Trost et al. have recently found a ruthenium‐catalyzed reaction, in which COD functions as bis‐homodiene and undergoes a cyclization with alkynes to form derivatives of the tricyclo‐[4.2.2.0 2, 5 ]dec‐7‐ene ( 1 ) in good yields. Thus, COD may now be considered as a synthetic building block.

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