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[SbN(SbCl) 3 (NSbCl 2 )(NSiMe 3 ) 2 ·SbCl 3 ], an Unusual Nitridoantimony Complex with a Heterocubane Structure
Author(s) -
Rhiel Markus,
Weller Frank,
Pebler Jürgen,
Dehnicke Kurt
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199405691
Subject(s) - character (mathematics) , imide , bearing (navigation) , atom (system on chip) , moisture , nitride , chemistry , materials science , medicinal chemistry , polymer chemistry , organic chemistry , physics , mathematics , computer science , layer (electronics) , geometry , astronomy , embedded system
A white, sparingly soluble, and moisture‐sensitive precipitate , formed almost quantitatively from SbCl 3 and N(SiMe 3 ) 3 , proved to be the title complex pictured here. In its heterocubane framework, only the N atom bearing the SbCl 3 group displays nitride character; the others bearing the SiMe 3 and SbCl 2 substituents have imide character.