[SbN(SbCl) 3 (NSbCl 2 )(NSiMe 3 ) 2 ·SbCl 3 ], an Unusual Nitridoantimony Complex with a Heterocubane Structure | Zendy

Rhiel Markus | Zendy; Weller Frank | Zendy; Pebler Jürgen | Zendy; Dehnicke Kurt | Zendy

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[SbN(SbCl) 3 (NSbCl 2 )(NSiMe 3 ) 2 ·SbCl 3 ], an Unusual Nitridoantimony Complex with a Heterocubane Structure

Author(s) -

Rhiel Markus,

Weller Frank,

Pebler Jürgen,

Dehnicke Kurt

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199405691

Subject(s) - character (mathematics) , imide , bearing (navigation) , atom (system on chip) , moisture , nitride , chemistry , materials science , medicinal chemistry , polymer chemistry , organic chemistry , physics , mathematics , computer science , layer (electronics) , geometry , astronomy , embedded system

A white, sparingly soluble, and moisture‐sensitive precipitate , formed almost quantitatively from SbCl 3 and N(SiMe 3 ) 3 , proved to be the title complex pictured here. In its heterocubane framework, only the N atom bearing the SbCl 3 group displays nitride character; the others bearing the SiMe 3 and SbCl 2 substituents have imide character.

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