Reactions at Both Ends of a Dimetalated Olefin: CS 2  Insertion into and Atom Transfer Reactions of [Re(CO) 4 ‐{ trans ‐μ‐HCC(CO 2 Me)}Re(CO) 4 (NCMe)] | Zendy

Adams Richard D. | Zendy; Chen Linfeng | Zendy; Wu Wengan | Zendy

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Reactions at Both Ends of a Dimetalated Olefin: CS 2 Insertion into and Atom Transfer Reactions of [Re(CO) 4 ‐{ trans ‐μ‐HCC(CO 2 Me)}Re(CO) 4 (NCMe)]

Author(s) -

Adams Richard D.,

Chen Linfeng,

Wu Wengan

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199405681

Subject(s) - chemistry , olefin fiber , molecule , atom (system on chip) , pyridine , stereochemistry , crystallography , medicinal chemistry , catalysis , organic chemistry , computer science , embedded system

First a functionalized CC bond, then a CE bond (E O, S) are formed at the methyl propenate ligands in the title compound to afford 1 . This takes place when the starting material is treated with CS 2 and subsequently with pyridine‐ N ‐oxide or ethylenesulfide. In this reaction the CS 2 molecule is inserted exclusively into the ReC α bond of the starting material, the O or S atom into the ReC β bond of the intermediate.

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