Premium
Ring Opening of Cyclopropane at 10 K
Author(s) -
Maier Günther,
Senger Stefan
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199405581
Subject(s) - cyclopropane , cyclopropene , ring (chemistry) , thermal , chemistry , photochemistry , medicinal chemistry , organic chemistry , physics , thermodynamics
“Thermal” reactions at 10 K? How is it posible to achieve a thermal ring‐opening of cyclopropane [Eq. (a)] and cyclopropene (both reactions have substantial energy barriers) at such extremely low temperatures? The answer is to be found in this communications.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom