Premium
Molecular Solids as Ligands in Organometallic Chemistry: [Cp 6 * Ti 6 Na 7 F 19 ·2.5thf] (Cp * C 5 Me 5 ) and [Cp 4 * Ti 4 Mg 2 F 12 ·7thf], Links Between Ionic Solids and Organometallic Compounds
Author(s) -
Liu FengQuan,
Kuhn Annja,
HerbstIrmer Regine,
Stalke Dietmar,
Roesky Herbert W.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199405551
Subject(s) - group 2 organometallic chemistry , chemistry , magnesium , solubility , inorganic chemistry , sodium , nuclear chemistry , crystallography , molecule , organic chemistry
Central NaF and MgF 2 frameworks are present in the title compounds obtained from the reaction of [Cp * TiF 3 ] (Cp C 5 Me 5 ) with elemental sodium and magnesium, respectively. In these reactions Ti IV is reduced to Ti III . The Cp * Ti units function as organometallics shields around the cagelike core and are responsible for the high solubility of the compounds.