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Novel Carbon Compounds with “Naked” C n Units
Author(s) -
Lang Heinrich
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199405471
Subject(s) - carbyne , transition metal , carbon fibers , polymer , chemistry , link (geometry) , metal , crystallography , materials science , stereochemistry , polymer chemistry , combinatorics , mathematics , organic chemistry , composite material , composite number , carbene , catalysis
1,3‐Dimetallaallenes 1 or carbyne complexes 2 are the simplest examples of compounds in which different transition metal complex fragments or units of main group elements are terminally bound to C n bridges. Polymers such as 3 with C 4 bridges which link d 8 ML 2 building blocks are of particular interest as materials with novel properties.