Premium
Silane Nitrile: Matrix Isolation, Adduct with Hydrogen
Author(s) -
Maier Günther,
Glatthaar Jörg
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199404731
Subject(s) - nitrile , silane , matrix isolation , adduct , cyanide , hydrogen cyanide , isocyanide , silicon , chemistry , matrix (chemical analysis) , carbon fibers , organic chemistry , materials science , molecule , composite material , chromatography , composite number
How do carbon and silicon chemistry differ? For example, the cyanide⇌isocyanide equilibrium is completely reversed in the sila series. According to calculations silane nitrile ( 2 ) is higher in energy than its isomer 1 , which has been known for much longer. The matrix isolation of 2 has now been achieved; 2 is the first silicon compound of the nitrile type.