Silane Nitrile: Matrix Isolation, Adduct with Hydrogen | Zendy

Maier Günther | Zendy; Glatthaar Jörg | Zendy

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Silane Nitrile: Matrix Isolation, Adduct with Hydrogen

Author(s) -

Maier Günther,

Glatthaar Jörg

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199404731

Subject(s) - nitrile , silane , matrix isolation , adduct , cyanide , hydrogen cyanide , isocyanide , silicon , chemistry , matrix (chemical analysis) , carbon fibers , organic chemistry , materials science , molecule , composite material , chromatography , composite number

How do carbon and silicon chemistry differ? For example, the cyanide⇌isocyanide equilibrium is completely reversed in the sila series. According to calculations silane nitrile ( 2 ) is higher in energy than its isomer 1 , which has been known for much longer. The matrix isolation of 2 has now been achieved; 2 is the first silicon compound of the nitrile type.

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