Fullerene Chemistry in Three Dimensions: Isolation of Seven Regioisomeric Bisadducts and Chiral Trisadducts of C 60  and Di(ethoxycarbonyl)methylene | Zendy

Hirsch Andreas | Zendy; Lamparth Iris | Zendy; Karfunkel Heinrich R. | Zendy

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Fullerene Chemistry in Three Dimensions: Isolation of Seven Regioisomeric Bisadducts and Chiral Trisadducts of C 60 and Di(ethoxycarbonyl)methylene

Author(s) -

Hirsch Andreas,

Lamparth Iris,

Karfunkel Heinrich R.

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199404371

Subject(s) - fullerene , methylene , chemistry , isolation (microbiology) , stereochemistry , computational chemistry , organic chemistry , combinatorial chemistry , bioinformatics , biology

Remarkably high selectivity marks the reaction of a regioisomeric bisadduct of C 60 with defined structure to give the D 3 ‐symmetric trisadduct 1 . This and other results—for example, the isolation of the seven stable isomers of C 62 (COOEt) 4 (of the eight possible)—were obtained in the first systematic study of the regiochemistry of C 60 with both experimental and theoretical methods.

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