Synthesis and Structure of an Oxovanadium( V )—Organophosphonate Cluster Encapsulating a Chloride Ion: [ClV 7 O 12 (O 3 PC 6 H 5 ) 6 ] 2− | Zendy

Chang YuanDa | Zendy; Salta Jose | Zendy; Zubieta Jon | Zendy

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Synthesis and Structure of an Oxovanadium( V )—Organophosphonate Cluster Encapsulating a Chloride Ion: [ClV 7 O 12 (O 3 PC 6 H 5 ) 6 ] 2−

Author(s) -

Chang YuanDa,

Salta Jose,

Zubieta Jon

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199403251

Subject(s) - ion , cluster (spacecraft) , crystallography , tetrahedron , chloride , chemistry , atom (system on chip) , chlorine , stereochemistry , topology (electrical circuits) , combinatorics , computer science , organic chemistry , mathematics , embedded system , programming language

A hollow sphere, constructed from VO 5 square pyramids and PhPO 3 tetrahedra , which encapsulates a chlorine atom—this is an apt description of the anion in 1 (structure shown on the right). At first glance this anion, with its spheroidal structure, appears similar to known polyoxoanions; however, closer inspection reveals the striking structural similarities to analogous binuclear building blocks and to the layered solid VO(O 3 PR), H 2 O, which extend beyond purely topological relationships to chemical behavior.

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