[K([18]crown‐6)] +  [Mo 4 (μ 4 ‐H) (OCH 2  t Bu) 12 ] − , the First Alkoxidohydrido Cluster of Molybdenum, Evidence for a Rare, if not the First, Example of a μ 4 ‐Hydride | Zendy

Budzichowski Theodore A. | Zendy; Chisholm Malcolm H. | Zendy; Huffman John C. | Zendy; Eisenstein Odile | Zendy

Premium

[K([18]crown‐6)] + [Mo 4 (μ 4 ‐H) (OCH 2 t Bu) 12 ] − , the First Alkoxidohydrido Cluster of Molybdenum, Evidence for a Rare, if not the First, Example of a μ 4 ‐Hydride

Author(s) -

Budzichowski Theodore A.,

Chisholm Malcolm H.,

Huffman John C.,

Eisenstein Odile

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199401911

Subject(s) - cluster (spacecraft) , ion , crystallography , ligand (biochemistry) , chemistry , receptor , biochemistry , organic chemistry , computer science , programming language

A Mo 4 butterfly cluster in which a hydrido ligand is bonded to all four metal atoms probably occurs in the anion of the title complex. This anion is accessible from [Mo 2 (OCH 2 t Bu) 6 ] and K[B s Bu 3 H] in the presence of [18]crown‐6. As shown schematically below the H‐ligand serves to couple two Mo Mo units to generate the Mo 4 (μ 4 ‐H)‐containing anion.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research