(Pentafluoro‐λ 6 ‐sulfanyl)cyclopentadiene and Cyclopentadienylidenetetrafluoro‐λ 6 ‐sulfane | Zendy

Klauck Axel | Zendy; Seppelt Konrad | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

(Pentafluoro‐λ 6 ‐sulfanyl)cyclopentadiene and Cyclopentadienylidenetetrafluoro‐λ 6 ‐sulfane

Author(s) -

Klauck Axel,

Seppelt Konrad

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199400931

Subject(s) - cyclopentadiene , chemistry , trigonal bipyramidal molecular geometry , ring (chemistry) , resonance (particle physics) , ylide , sulfanyl , aromaticity , crystallography , stereochemistry , molecule , crystal structure , organic chemistry , catalysis , physics , particle physics

A rigid trigonal‐bipyramidal arrangement of substituents and consequently a rigid CS bond are found in thione 2 at temperatures up to 180 °C. Compound 2 does not occur in the resonance‐stabilized ylide‐type resonance structure with an aromatic five‐membered ring. It is formed by elimination of HF from cyclopentadiene 1 , the anion of which should display a diverse coordination chemistry.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research