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A Hexanuclear Gold( I ) Complex: [{(Ph 3 PAu) 2 C(PPh 2 AuPPh 2 )} 2 ](ClO 4 ) 2
Author(s) -
Fernández Eduardo J.,
Gimeno M. Concepción,
Jones Peter G.,
Laguna Antonio,
Laguna Mariano,
LopezdeLuzuriaga José M.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199400871
Subject(s) - chemistry , ring (chemistry) , crystallography , atom (system on chip) , oxygen atom , carbon fibers , analytical chemistry (journal) , materials science , molecule , chromatography , organic chemistry , computer science , composite number , composite material , embedded system
The pale yellow, air‐ and moisture‐stable hexanuclear Au 1 complex 1 contains a central Au 2 C 2 P 4 eight‐membered ring with two additional AuPPh 3 groups coordinated to each peripheral carbon atom. The Au‐Au distances in 1 are short and all Au atoms linearly coordinated.