A “Branched‐Monomer Approach” for the Rapid Synthesis of Dendimers | Zendy

Wooley Karen L. | Zendy; Hawker Craig J. | Zendy; Fréchet Jean M. J. | Zendy

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A “Branched‐Monomer Approach” for the Rapid Synthesis of Dendimers

Author(s) -

Wooley Karen L.,

Hawker Craig J.,

Fréchet Jean M. J.

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199400821

Subject(s) - dendrimer , monomer , macromolecule , ether , bromide , williamson ether synthesis , polymer chemistry , chemistry , materials science , polymer science , organic chemistry , polymer , biochemistry

An accelerated route to the synthesis of dendritic macromolecules through the use of fractal components larger than the repeating unit is described. The first‐generation bromide 1 and the second‐generation novel branched AB 4 monomer 2 can be used to prepare a highly regular fifth‐generation poly(ether ester) dendrimer ( M r = 9371) in only three synthetic steps.

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