Cooperativity in Rh 2  Complexes: High Catalytic Activity and High Regioselectivity in the Hydroformylation of Olefins | Zendy

SüssFink Georg | Zendy

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Cooperativity in Rh 2 Complexes: High Catalytic Activity and High Regioselectivity in the Hydroformylation of Olefins

Author(s) -

SüssFink Georg

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199400671

Subject(s) - hydroformylation , cooperativity , regioselectivity , catalysis , ligand (biochemistry) , chemistry , intramolecular force , homogeneous , rhodium , stereochemistry , combinatorial chemistry , organic chemistry , receptor , physics , biochemistry , thermodynamics

A breakthrough in tailor‐made homogeneous catalysts has been achieved by Stanley et al., who synthesized the rac ‐Rh 2 complex 1 with a new tetraphosphane ligand, which catalyzes the hydroformylation of olefins with a high activity and extremely selectively. The combination of these important catalytic properties is traced back to the intramolecular interaction of the two Rh centers fixed by the ligand matrix.

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