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[(I 6 Te 2 )Nb(Te 2 ) 2 )Nb(Te 2 I 6 )], a Metal Complex with Halochalcogenate Ligands
Author(s) -
Leist Astrid,
Tremel Wolfgang
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199317511
Subject(s) - disproportionation , crystallography , metal , chemistry , halo , inorganic chemistry , materials science , physics , catalysis , biochemistry , organic chemistry , quantum mechanics , galaxy
One iodotellurate(II) ligand is present in the title compound 1 (structure shown on the right). Compound 1 can be prepared from the elements by reactions at high temperature. Halo anions of chalcogenides were previously only known in the free form and were prepared in solution by disproportionation of the tetrahalides. ○ Nb, • Te, ○ I.