Unprecedented Cage‐Opening of P 4 S 3  Initiated by an Organometallic Radical: Synthesis and Structure of [Cp 4 Cr 4 (CO) 9 (P 4 S 3 )] | Zendy

Goh Lai Yoong | Zendy; Chen Wei | Zendy; Wong Richard C. S. | Zendy

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Unprecedented Cage‐Opening of P 4 S 3 Initiated by an Organometallic Radical: Synthesis and Structure of [Cp 4 Cr 4 (CO) 9 (P 4 S 3 )]

Author(s) -

Goh Lai Yoong,

Chen Wei,

Wong Richard C. S.

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199317281

Subject(s) - chemistry , cleavage (geology) , cage , stereochemistry , crystallography , bond cleavage , fragmentation (computing) , medicinal chemistry , combinatorics , materials science , mathematics , organic chemistry , computer science , catalysis , fracture (geology) , composite material , operating system

A CrP 4 S bicyclo[2.1.11 system is the central unit of the title complex 1 (the Cp ligands are omitted for clarity from the structure shown on the right). Compound 1 forms in the reaction of P 4 S 3 with the 17‐electron complex fragment [CpCr(CO) 3 ]; here, the P 4 S 3 cage undergoes multiple bond cleavage without fragmentation, accompanied by structural rearrangement.

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