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Organometallic Ferrocenyl Polymers Displaying Tunable Cooperative Interactions between Transition Metal Centers
Author(s) -
Foucher Daniel A.,
Honeyman Charles H.,
Nelson James M.,
Tang Ben Zhong,
Manners Ian
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199317091
Subject(s) - ferrocene , polymer , transition metal , electrochemistry , polymer chemistry , materials science , metal , chemistry , nanotechnology , combinatorial chemistry , organic chemistry , electrode , catalysis , composite material , metallurgy
Due to a dependency on the element in the spacer and its substituents , the extent of the interactions between the ferrocene units of the polymer backbone of 1 and 2 can be varied. The electrochemical behavior of 3 in which the ferrocene units are separated by C 2 bridges shows that the cooperative interactions are much less significant for this polymer.