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A Hexanuclear Organogallium Fluoride Oxide
Author(s) -
Neumüller Bernhard,
Gahlmann Frank
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199317011
Subject(s) - octahedron , fluorine , fluoride , chemistry , oxide , gallium , crystallography , hydrolysis , oxygen atom , inorganic chemistry , crystal structure , molecule , organic chemistry
A distorted gallium octahedron , whose eight faces are capped by fluorine and oxygen atoms, is a description of the structure of Mes 6 Ga 6 F 4 O 4 ( 1 ) (see picture in which only the ipso C atoms of the mesityl groups are shown); 1 is accessible from [Mes 2 GaF] 2 and H 2 O. The bulky organo substituents shield the central GaFO framework from further hydrolysis.