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Decamethylaluminocenium, a π‐Stabilized R 2 Al + Cation
Author(s) -
Dohmeier Carsten,
Schnöckel Hansgeorg,
Schneider Uwe,
Ahlrichs Reinhart,
Robl Christian
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199316551
Subject(s) - crystallography , chemistry , spectroscopy , materials science , physics , quantum mechanics
The first sandwich complex of an element from the third main group , the cation in 1, has been synthesized and characterized by spectroscopy and X‐ray crystallography (see picture). This cation is stabilized by π interactions, and the Cp * ligands are staggered.