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The First Heteroallyl Metal Complexes of Arsenic with the Coordination Number 2
Author(s) -
Wirringa Uwe,
Roesky Herbert W.,
Noltemeyer Mathias,
Schmidt HansGeorg
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199316281
Subject(s) - deprotonation , arsenic , coordination complex , coordination number , metal , chemistry , inorganic chemistry , combinatorial chemistry , organic chemistry , ion
Isotypical structures and great stability characterize the heteroallyl complexes 1 and 2 in which As is dicoordinate. The synthesis of the complexes from 3 by deprotonation with M(N(SiMe 3 ) 2 ) 2 should also be transferrable to other heteroallyl systems.