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New AsS Cage Structures with Organometallic Components Formed by Complex‐Induced Realgar Fragmentation
Author(s) -
Brunner Henri,
Poll Ludwig,
Wachter Joachim,
Nuber Bernhard
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199316271
Subject(s) - realgar , cage , fragmentation (computing) , chemistry , organometallic chemistry , stereochemistry , crystallography , materials science , crystal structure , nanotechnology , mineralogy , mathematics , computer science , combinatorics , operating system
The significance of AsS ligands in the construction of AsS cage structures with an As 2 S 3 framework and organometallic building blocks is documented for the first time in the thermal conversion of 1 to give 2 and 3 . Complex 1 can be considered as the initial product of the complex‐induced realgar fragmentation with [{Cp × Co(CO)} 2 ] (Cp × = C 5 Me 4 Et).