New AsS Cage Structures with Organometallic Components Formed by Complex‐Induced Realgar Fragmentation | Zendy

Brunner Henri | Zendy; Poll Ludwig | Zendy; Wachter Joachim | Zendy; Nuber Bernhard | Zendy

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New AsS Cage Structures with Organometallic Components Formed by Complex‐Induced Realgar Fragmentation

Author(s) -

Brunner Henri,

Poll Ludwig,

Wachter Joachim,

Nuber Bernhard

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199316271

Subject(s) - realgar , cage , fragmentation (computing) , chemistry , organometallic chemistry , stereochemistry , crystallography , materials science , crystal structure , nanotechnology , mineralogy , mathematics , computer science , combinatorics , operating system

The significance of AsS ligands in the construction of AsS cage structures with an As 2 S 3 framework and organometallic building blocks is documented for the first time in the thermal conversion of 1 to give 2 and 3 . Complex 1 can be considered as the initial product of the complex‐induced realgar fragmentation with [{Cp × Co(CO)} 2 ] (Cp × = C 5 Me 4 Et).

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