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Nitrosyl Azide, N 4 O, an Intrinsically Unstable Oxide of Nitrogen
Author(s) -
Schulz Axel,
TornieporthOetting Inis C.,
Klapötke Thomas M.
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199316101
Subject(s) - azide , raman spectroscopy , ab initio , nitrogen , oxide , spectroscopy , chemistry , crystallography , materials science , computational chemistry , organic chemistry , physics , optics , quantum mechanics
The seventh nitrogen oxide, N 4 O , was prepared, isolated, and characterized by means of Raman spectroscopy. The bands could be unambiguously assigned with the aid of ab initio calculations incorporating electron correlations. The picture on the right shows the chainlike structure of N 4 O, which consists of a nitrosyl and an azide unit.