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Tris(chlorodimethylstannyl)amine, a Molecule with a Planar Sn 3 N Skeleton Stabilized by Intramolecular Sn‐Cl‐Sn Bridges
Author(s) -
Kober Christian,
Kroner Jürgen,
Storch Wolfgang
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199316081
Subject(s) - intramolecular force , molecule , amine gas treating , chemistry , crystallography , planar , tris , nuclear magnetic resonance spectroscopy , skeleton (computer programming) , stereochemistry , organic chemistry , biochemistry , computer graphics (images) , computer science , programming language
Nearly D 3h symmetry, a planar Sn 3 N framework , almost symmetrical SnClSn bridges and extremely short SnN bonds‐these are the features of the skeleton of (ClMe 2 Sn) 3 N 1 . This unusual structure has been characterized by NMR spectroscopy, quantum chemical calculations, and X‐ray structural analysis. No indications of SnN (dp)π bond participation were found.