The Behavior of Cp * MoBr/Br 2  Redox Systems: The Unusual Structure of [(Cp       *    2    Mo 2 Br 4 )2(Cp * MoBr 4 ) 3 ], a Compound Containing Mo  III  , Mo  IV  , and Mo  V | Zendy

Desai Jahanvi U. | Zendy; Gordon John C. | Zendy; Kraatz HeinzBernhard | Zendy; OwensWaltermire Beth E. | Zendy; Poli Rinaldo | Zendy; Rheingold Arnold L. | Zendy

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The Behavior of Cp * MoBr/Br 2 Redox Systems: The Unusual Structure of [(Cp * 2 Mo 2 Br 4 )2(Cp * MoBr 4 ) 3 ], a Compound Containing Mo III , Mo IV , and Mo V

Author(s) -

Desai Jahanvi U.,

Gordon John C.,

Kraatz HeinzBernhard,

OwensWaltermire Beth E.,

Poli Rinaldo,

Rheingold Arnold L.

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199314861

Subject(s) - bromine , redox , valence (chemistry) , molybdenum , ion , crystal structure , chemistry , crystallography , inorganic chemistry , organic chemistry

A Mo IV anion, a neutral Mo V complex, and a mixed‐valence Mo III /Mo IV cation are found within the same crystal of the title compound 1 , which is prepared by the reaction of [(Cp * MoBr 2 ) 2 ] with bromine in benzene. The coexistence of three oxidation states of molybdenum within 1 and the formation of 1 is rationalized based on the particular redox behavior of the individual constituents of the redox system Cp * MoBr/Br 2 . The anion [Cp * MoBr 4 ] − in 1 is shown on the right. Cp * η 5 ‐C 5 Me 5 .

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