Carbenerhodium Complexes with Diaryl‐ and Aryl(alkyl)carbenes as Ligands: The Missing Link in the Series of the Double Bond Systems  trans ‐[RhCl{ C(C) n RR′}(L) 2 ] Where  n   0, 1, and 2 | Zendy

Schwab Peter | Zendy; Mahr Norbert | Zendy; Wolf Justin | Zendy; Werner Helmut | Zendy

Premium

Carbenerhodium Complexes with Diaryl‐ and Aryl(alkyl)carbenes as Ligands: The Missing Link in the Series of the Double Bond Systems trans ‐[RhCl{ C(C) n RR′}(L) 2 ] Where n  0, 1, and 2

Author(s) -

Schwab Peter,

Mahr Norbert,

Wolf Justin,

Werner Helmut

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199314801

Subject(s) - carbene , ligand (biochemistry) , alkyl , aryl , chemistry , heteroatom , stereochemistry , medicinal chemistry , organic chemistry , catalysis , receptor , biochemistry

That compounds bearing homologous ligands —here P i Pr 3 and Sb i Pr 3 —can behave differently is underlined by the synthesis of the first carbenerhodium(i) complexes in which the carbene is not stabilized by a heteroatom. Compound 1 (characterized by X‐ray structural analysis) undergoes a variety of interesting ligand displacement reactions, giving, for example, 2 (L Sb i Pr 3 , CO, CN t Bu) and 3 . Diphenylketene is obtained by coupling of the carbene ligand with CO.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research