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A Nickel‐Anthracene Complex Having η 3 and η 4 Coordination in One Crystal
Author(s) -
Boese Roland,
Stanger Am,
Stellberg Peter,
Shazar Anat
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199314751
Subject(s) - anthracene , nickel , molecule , non blocking i/o , crystal (programming language) , crystal structure , crystallography , chemistry , coordination complex , stereochemistry , photochemistry , computer science , organic chemistry , catalysis , metal , programming language
Two independent isomeric molecules in one crystal. This was the surprising result of the X‐ray structural analysis of 1 . Both molecules can be considered as representatives of transition states of the η 2 ⇇η 2 rearrangement that is common in Ni o –arene complexes.